Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10242958 | Catalysis Communications | 2005 | 6 Pages |
Abstract
Sulphur poisoning and regeneration of a commercial NSR catalyst by SO2 were investigated in dependence on temperature and λ value. The amount of desorbed sulphur compounds during lean-rich regeneration cycles was found to increase with decreasing λ value (0.99-0.94) at constant temperature and with increasing temperature (660-720 °C) at constant λ value. At a regeneration temperature of 660 °C, removed sulphur components comprises mainly SO2 at λ values near 1, whereas H2S and COS are released at lower λ values. At higher regeneration temperatures and low λ values more SO2 is released, but COS and H2S formation also increases.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
E. Schreier, R. Eckelt, M. Richter, R. Fricke,