Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10244311 | Journal of Catalysis | 2012 | 9 Pages |
Abstract
⺠Rate per proton in different zeolite environments for C2H4 and C3H6 methylation. ⺠Rate is zero-order in dimethyl ether pressure and first-order in olefin pressure. ⺠Same mechanism, but rates differ by a factor of 30 across zeolites. ⺠Surface methoxide species are formed during steady-state operation; no direct C-H activation.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Ian M. Hill, Saleh Al Hashimi, Aditya Bhan,