Article ID Journal Published Year Pages File Type
10244311 Journal of Catalysis 2012 9 Pages PDF
Abstract
► Rate per proton in different zeolite environments for C2H4 and C3H6 methylation. ► Rate is zero-order in dimethyl ether pressure and first-order in olefin pressure. ► Same mechanism, but rates differ by a factor of 30 across zeolites. ► Surface methoxide species are formed during steady-state operation; no direct C-H activation.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
Authors
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