| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10244323 | Journal of Catalysis | 2012 | 12 Pages |
Abstract
⺠V-MIL-47 can be a selective catalyst in the epoxidation of cyclohexene. ⺠Water should be avoided as the solvent for the peroxide. ⺠Leaching is negligible and the structural integrity of the MOF is preserved. ⺠Computational studies show the necessity of breaking of two V-terephthalic bonds. ⺠Two competitive cyclohexene epoxidation pathways are discussed.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Karen Leus, Matthias Vandichel, Ying-Ya Liu, Ilke Muylaert, Jan Musschoot, Steven Pyl, Henk Vrielinck, Freddy Callens, Guy B. Marin, Christophe Detavernier, Paul V. Wiper, Yaroslav Z. Khimyak, Michel Waroquier, Veronique Van Speybroeck,