| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10244656 | Journal of Catalysis | 2005 | 6 Pages |
Abstract
A new chiral macrocyclic Mn(III)-salen complex has been prepared with two salicylidene moieties linked together to their 3 and 3â² positions by an aliphatic polyether bridge. This complex provides a highly enantioselective (up to 93%) catalyst for epoxidation of cis-disubstituted olefins with sodium hypochlorite as an oxygen atom donor and can be recycled up to three times without significant loss in performance.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Alexandre Martinez, Catherine Hemmert, Bernard Meunier,