Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10244692 | Journal of Catalysis | 2005 | 5 Pages |
Abstract
At present Melonal (2,6-dimethyl-5-hepten-1-al) fragrance is industrially produced by a Darzens reaction from 6-methyl-5-hepten-2-one, with ethylchloroacetate as reagent. We present here a novel halogen-free synthesis strategy that involves the chemoselective oxidation of Citral (3,7-dimethyl-6-octen-1-al), a common compound in the fragrance industry, with H2O2 and Sn-Beta or Sn-MCM-41 as catalysts. The performance of tin Lewis acid sites is compared with other potential catalytic sites, and it is found that aluminium Brønsted acid sites and zirconium or titanium Lewis acid sites are less efficient and selective than Sn. In the case of Ti, epoxidation by-products could be found. The re-usability of Sn-Beta zeolite is discussed, as is the heterogeneity of the reaction.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Avelino Corma, Sara Iborra, MarÃa Mifsud, Michael Renz,