Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10246924 | Journal of Molecular Catalysis A: Chemical | 2005 | 5 Pages |
Abstract
The formation of highly active ruthenium based catalysts from solid RuCl3 in the presence of phosphines affords a simple route to formamide production from amines, hydrogen and carbon dioxide; the structure of the in situ formed active complex was elucidated by X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectroscopy.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Markus Rohr, Jan-Dierk Grunwaldt, Alfons Baiker,