| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10247092 | Journal of Molecular Catalysis A: Chemical | 2005 | 4 Pages |
Abstract
A number of tin(II) complexes, prepared in situ from tin(II) triflate and pyridine derivatives (2,2â²:6â²,2â³-terpyridine, 1,10-phenanthroline, 2,2â²-bipyridine, dipyridylmethane, 2-(thiophen-2-yl)pyridine and 2-(2-diphenylphosphinophenyl)-5,6,7,8-tetrahydroquinoline), have been used as chiral catalysts for the reduction of acetophenone in the presence of polymethylhydrosiloxane (PMHS). Yields up to 82% and enantioselectivities up to 19% have been obtained.
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Authors
Giorgio Chelucci, Daniele Muroni, Ilaria Manca,