Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10248716 | Solar Energy Materials and Solar Cells | 2014 | 5 Pages |
Abstract
We demonstrate cost-effective, indium tin oxide (ITO)-free organic solar cells (OSCs) fabricated with a silver nanowire (AgNW)-poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) composite electrode. The composite films were prepared with a one-step spray-coating of a mixture composed of AgNW and a highly conductive, dimethylsulfoxide (DMSO)-treated PEDOT:PSS (hcPEDOT). The film-thickness, optical transmittance, and sheet resistance of AgNW-hcPEDOT hybrid electrodes were easily controlled by varying the spray deposition time. With AgNW-hcPEDOT composite electrodes, the devices exhibited high power conversion efficiencies of up to 2.16% under 100Â mWÂ cmâ2 and AM 1.5G illumination conditions. In addition, the surface of the AgNW-hcPEDOT composite electrodes was further smoothened with an additional spray-coated PEDOT:PSS buffer layer, leading to reduced shorting and improved cell-efficiency. As a result, the best performing devices with a AgNW-hcPEDOT electrode and spray-coated PEDOT buffer exhibited efficiencies of up to 2.65%, which approaches that of conventional ITO-based devices. These results indicate that the one-step spray-coated AgNW-hcPEDOT composite-based film is a viable alternative to the high-cost and vacuum-deposited ITO for mass-production and low-cost roll-to-roll based solar cells.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Yong-Jin Noh, Seok-Soon Kim, Tae-Wook Kim, Seok-In Na,