Manganese(III) porphyrin supported onto multi-walled carbon nanotubes for heterogeneous oxidation of synthetic textile dyes and 2,6-dimethylphenol by tert-butyl hydroperoxide

Manganese porphyrin has been supported onto multi-walled carbon nanotubes (Mn(TCPP)OAc@MWCNT) and characterized by powder X-ray diffraction, FT-IR, atomic absorption and UV-vis spectroscopy, field emission scanning electron microscopy (FE-SEM) and also thermogravimetric analysis (TGA). The TGA curve shows that the nanocatalyst was thermally stable up to almost 350 °C. This catalyst was found to be able to oxidize different synthetic textile dyes in aqueous media over a wide pH range at ambient temperature with tert-butyl hydroperoxide (TBHP) as the oxygen source. The influence of some important parameters such as the initial pH of the dye solution, temperature and concentration of the catalyst, the oxidant and the co-catalyst were investigated. Also, the ability of this heterogeneous catalyst to oxidize 2,6-dimethylphenol (with excellent selectivity for quinone (86%)) with TBHP in acetonitrile was evaluated. The separation and recycling of the catalyst is simple and the catalyst can be used several successive cycles without significant decrease in catalytic activity.