Article ID Journal Published Year Pages File Type
10268934 Electrochimica Acta 2011 7 Pages PDF
Abstract
► Modeling electron transfer rate to electrode from redox via mediated bridge of atoms. ► Redox interaction of solvent modeled as classical harmonic oscillator bath. ► Both transient and rate constants are calculated. ► Negative differential resistance at high overpotential for thermal electron transfer. ► Dependency on chain length is analysed.
Keywords
Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
Preview
Transient behaviour of electron exchange between a molecular wire and a metal electrode
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