Article ID Journal Published Year Pages File Type
10268942 Electrochimica Acta 2011 9 Pages PDF
Abstract
► Spectroelectrochemical study on (5-R-4-oxothiazolidin)-N-phenylethanamide in DMSO. ► R=ethoxycarbonylethylidene (2), R=ethoxycarbonylmethyl (1). ► Proposed mechanism: common intermediate-dianion. ► Bielectronic reduction 2+2e-, or 1-2H+ in basic DMSO. ► E/Z isomerization, tautomerization, push-pull effect.
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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
Preview
Reactivity of substituted 4-oxothiazolidine derivatives in electron transfer reactions: A spectroelectrochemical study and mechanistic aspects
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