Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10271382 | Fluid Phase Equilibria | 2005 | 9 Pages |
Abstract
Experimental solubility results are compared with values calculated by means of the Wilson, UNIQUAC ASM and two NRTL equations utilizing parameters derived from SLE results. The existence of a solid-solid first-order phase transition in 18-crown-6 ether has been taken into consideration in the calculations. The correlation of the solubility data has been obtained with the average root-mean-square deviation of temperature ÏTÂ =Â 0.9Â K with UNIQUAC ASM and two NRTL equations and 0.6Â K with the Wilson equation.
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Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
U. DomaÅska, J. Åachwa,