Article ID Journal Published Year Pages File Type
10275703 Journal of Electroanalytical Chemistry 2011 9 Pages PDF
Abstract
► Voltammetry under Butler-Volmer and Marcus-Hush electrode kinetic models are compared. ► Notable discrepancies are found for slow kinetics, short pulses and microelectrodes. ► These differences can affect significantly the extraction of kinetic parameters. ► Striking phenomena predicted with Butler-Volmer are studied with Marcus-Hush.
Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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