Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10275703 | Journal of Electroanalytical Chemistry | 2011 | 9 Pages |
Abstract
⺠Voltammetry under Butler-Volmer and Marcus-Hush electrode kinetic models are compared. ⺠Notable discrepancies are found for slow kinetics, short pulses and microelectrodes. ⺠These differences can affect significantly the extraction of kinetic parameters. ⺠Striking phenomena predicted with Butler-Volmer are studied with Marcus-Hush.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Eduardo Laborda, Martin C. Henstridge, Angela Molina, Francisco MartÃnez-Ortiz, Richard G. Compton,