Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10275725 | Journal of Electroanalytical Chemistry | 2005 | 13 Pages |
Abstract
In a previous paper [J. Electroanal. Chem. 578 (2005) 159] we have presented the general equations for a model of ion transfer reactions across the oil|water interface assisted by a neutral protonatable ligand. Our analysis focused mainly on the effect of water autoprotolysis on transfer processes. In this second part, cation transfer assisted by a protonatable ligand is described. The competitive reaction for a ligand between metal cation and proton is presented. The results are analyzed for different zones determined by the cation/ligand and proton/ligand concentration ratios.
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Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
S.A. Dassie,