Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10275818 | Journal of Electroanalytical Chemistry | 2005 | 5 Pages |
Abstract
New conducting copolymers have been synthesized via electrochemical oxidation of thiophene (Th) in the presence of monomer bis(2-thienyl)ethyl (I). Cyclic voltammetry (CV) studies showed that the presence of monomer I in the electrolytic solution greatly changes the CV behaviour of the formation of the polythiophene films. It is found that the increasing ratio of I was found to decrease electroactivity of copoly(I-Th). Electrochemical synthesis of copolymer films was achieved via constant potential electrolysis (CPE) in an electrolytic solution containing 0.1Â M tetrabutylammonium hexafluorophosphate (TBAPF6) dissolved in CH3CN. Spectroelectrochemical (SPEL) properties of the films were investigated using UV-vis spectroscopic technique.
Keywords
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Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Atilla Cihaner, Ahmet M. Ãnal,