Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10275898 | Journal of Electroanalytical Chemistry | 2005 | 9 Pages |
Abstract
In both media, linear relationships between EpIc (potential of first cathodic wave), Eredox (for aprotic) and Hammett substituent constants (Ïp, Ïâ) were observed. The reduction potentials correlate considerably better with (Ïp, Ïâ), showing the strong influence of resonance factors in the mechanism of reduction.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Francine Santos de Paula, Ãcio Matias Sales, Maura Vallaro, Roberta Fruttero, MarÃlia O.F. Goulart,