| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10276210 | Journal of Electroanalytical Chemistry | 2005 | 8 Pages |
Abstract
In this work, a novel route for fabrication of platinum-polyaniline nanofilms at a liquid|liquid interface is proposed. This method synthesizes Pt nanoparticles incorporated in conductive PANI by reduction of H2PtCl6 to Pt nanoparticles and chemical oxidation polymerization of aniline simultaneously. The liquid|liquid interface offers a unique microenvironment for confining the 2D growth of PANI to form Pt-PANI nanofilms. The Pt-PANI nanofilms are characterized by field emission scanning electron microscopy, UV-Vis absorption spectroscopy, FTIR spectroscopy, X-ray photoelectron spectroscopy, 1H NMR spectroscopy and electrochemical impedance spectra. The Pt-PANI nanofilms show enhanced electrical conductivity compared to the chemically polymerized PANI. The conductivity of Pt-PANI nanofilms is potential-dependent, which makes them promising reversibly potential-switchable materials.
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Authors
Longzhen Zheng, Jinghong Li,