Experimentally produced glass compared with that occurring at The Torr, NW Scotland, UK: vitrification through biotite melting

It is proposed that the vitrification in some Iron Age forts in NW Scotland can be explained through decomposition of micas (largely biotite) giving melts that react with or dissolve quartz and crystallise orthopyroxene and feldspars, so equating with the reaction biotite + quartz = sanidine + orthopyroxene + liquid. A sample of Moine semi-pelite has been experimentally melted at c. 850 °C demonstrating this breakdown reaction. A preserved thermal gradient across the sample reveals the progressive degradation of biotite towards the melting (upper) surface. Degradation is evident from the initial emphasis of mica cleavages in grains at the bottom of the sample, and then appearance and progressive increase in size of bubbles associated with biotite and melt towards the top of the sample. A chocolate-brown melt was produced as a coating on the upper surface and along micaceous layers. A near equivalent sample was located from the fort at The Torr that, whilst being more thoroughly affected by heat, with no unaffected biotite, preserved similar textures. Compositions of original Moine minerals are used to constrain the melts produced and melt evolution is tracked through quenched crystals. These include ternary feldspars as well as sanidine, spinels and orthopyroxene. Spot geochemical evidence demonstrates the heterogeneity of the melts, plus varying contributions of Ca and Na that could be attributed to the onset of reactions involving feldspars and other minerals from the original assemblage. It is thus concluded that a similar temperature to that of c. 850 °C derived in the experiment was reached in the vitrification process at The Torr in order to produce the glass observed.