Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10389694 | Separation and Purification Technology | 2015 | 6 Pages |
Abstract
Previous research showed that N,Nâ²-dimethyl-N,Nâ²-dicyclohexylthiodiglycolamide (DMDCHTDGA) in 1,2-dichloroethane is able to co-extract platinum(IV) and palladium(II) from concentrated hydrochloric acid solutions. Following a detailed study about Pt(IV), the present work focuses on the thorough investigation of Pd(II) extraction by DMDCHTDGA in toluene. The removal of Pd(II) is rather efficient from 0.5Â M to 5.5Â M HCl, and progressively decreases until 7.5Â M HCl. Pd(II) stripping is better achieved by an acidic thiourea solution, but ammonia aqueous phases can alternatively be used for some cases. Pd(II) extraction kinetics is relatively favored (5-15Â min). The robustness of DMDCHTDGA to extract Pd(II) has been confirmed through five successive reutilization experiments. The maximum loading capacity for Pd(II) reaches a 2.5 DMDCHTDGA:Pd(II) molar ratio. Pd(II) can selectively be recovered by DMDCHTDGA from 4.0Â M or 6.0Â M HCl complex mixtures containing equivalent concentrations of Pt(IV) and Rh(III), and fivefold Fe(III) and Al(III) concentrations, although with a slight Pt(IV) contamination.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Filtration and Separation
Authors
Osvaldo Ortet, Ana Paula Paiva,