Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10407115 | Materials Science in Semiconductor Processing | 2016 | 5 Pages |
Abstract
This paper highlights the effect of the operation temperature on the performance of a photovoltaic-biased electrosynthetic cell (PV-EC) device for solar hydrogen production based on a triple junction thin film silicon solar cell. The influence of the temperature in the range from 25 °C to 60 °C was studied individually for all components of the device: the solar cell, the hydrogen evolving cathode, the oxygen evolving anode, and the electrolyte. Based on the experimental data, the overall temperature-dependent current-voltage characteristics of the complete PV-EC device was modeled by merging the current-voltage characteristics of the individual components in an empirical series circuit model. We found that a decrease in the photovoltage of the solar cells with increasing temperature can be compensated by an improved electrochemical kinetics with temperature. This lead to a slight improvement in the performance of the integrated PV-EC device. Under an assumption of 100% faradaic efficiency, a maximum solar-to-hydrogen efficiency of 9.5% was found in 1 M KOH at an operation temperature of 50 °C.
Related Topics
Physical Sciences and Engineering
Engineering
Electrical and Electronic Engineering
Authors
Félix Urbain, Jan-Philipp Becker, Vladimir Smirnov, Jürgen Ziegler, Florent Yang, Bernhard Kaiser, Wolfram Jaegermann, Sascha Hoch, Artjom Maljusch, Uwe Rau, Friedhelm Finger,