Effect of reprocessing on shrinkage and mechanical properties of ABS and investigating the proper blend of virgin and recycled ABS in injection molding

In this research, the effect of reprocessing of acrylonitrile-butadiene-styrene (ABS) on the mechanical properties of the polymer was studied through a five-stage reprocessing. To this end, the injection mold of the standard samples was manufactured. Then, using an injection molding machine, all of the virgin material was processed. After sampling, the rest of the parts were ground and then reprocessed under the same conditions. In order to get a proper combinational ratio of virgin and recycled ABS with respect to shrinkage and mechanical properties, another experiment was designed. In order to do this, virgin material was blended with 20%, 35% and 50% of the recycled material. The blends were reprocessed and samples were obtained. Impact, tensile, flexural and shrinkage tests, selected from ASTM standard, were used to investigate the mechanical properties of the polymer as well as its shrinkage. Furthermore, viscosity test was used to investigate the changes in the structure of the polymer. As the reprocessing cycles increased, shrinkage decreased and tensile and flexural ultimate strengths increased, more in flexural strength than in tensile. While Young's modulus slightly increased, viscosity decreased and consequently molecular weight decreased too. The proper blend for the least shrinkage was 50% whereas the best mechanical properties were achievable by the 20% blend. The obtained results suggest that reprocessing causes polymer degradation which is a result of the break in the bonds of poly butadiene. Moreover, it can be concluded that reprocessing in ABS can lead to the loss of effectiveness of some additives.