Thermal mismatch induced disorder of beta-eucryptite and its effect on thermal expansion of beta-eucryptite/Al composites

In this paper, beta-eucryptite/Al composites with different volume fraction of beta-eucryptite particles (Euc/Al) were prepared by spark plasma sintering process. The microstructures of the composites were studied by transmission electron microscope. The phase compositions and thermal physical properties of the composites were analyzed by X-ray diffraction and thermal dilatometer. The change of peaks intensity ratio of beta-eucryptite (2 0 0) to beta-eucryptite (2 0 2) plane after 12 months of aging in room condition and at elevated temperature (40-300 °C) was used to characterize the disorder of beta-eucryptite, which was due to the high thermal mismatch stress in the composite. The results indicate that the disorder of beta-eucryptite can recover when the thermal mismatch stress in beta-eucryptite is released after 12 months of aging or at elevated temperature. Both compressive stress and tensile stress could induce the disorder of eucryptite (2 0 0) plane. The relationships among CTE behavior of the composite, the phase transformation of beta-eucryptite and the thermal mismatch stress were discussed.