Hyperpolarizability and two photon observation of imidazolium picrate

The computational calculation based on the density functional theory at the basis sets level has been employed to compute the first-order hyperpolarizability of the title material. The nonlinear optical properties of imidazolium picrate was assessed by a open aperture z-scan technique in which Nd:YAG laser pulse at 532 nm wavelength was used as excitation source. Laser damage threshold of the crystal was investigated with Nd:YAG assembly for multiple shots and reported. The changes were observed and analyzed on (0 1 1) and (0 0 1) planes.