| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10480590 | Physica A: Statistical Mechanics and its Applications | 2013 | 18 Pages |
Abstract
⺠Thermodynamics has no limit for systems with irreversible reactions whereas the kinetic equations have. ⺠We describe the multiscale limit of systems of reversible reactions when some of equilibrium concentrations tend to zero. ⺠We prove the extended principle of detailed balance for systems with some irreversible reactions. ⺠We find the dynamical consequences of the extended principle of detailed balance. ⺠We constructively describe the limit points for the closed systems with some irreversible reactions.
Related Topics
Physical Sciences and Engineering
Mathematics
Mathematical Physics
Authors
A.N. Gorban, E.M. Mirkes, G.S. Yablonsky,