| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10546685 | Journal of the American Society for Mass Spectrometry | 2005 | 9 Pages |
Abstract
The fragmentations and reactions of Diazinon and related compounds have been studied by electrospray ionization ion trap mass spectrometry. Several novel fragmentation and rearrangements have been observed, including an intramolecular thiono-thiolo rearrangement. The stability, in the gas-phase, of the protomers of 2-isopropyl-4-methyl-6-pyrimidinol has been demonstrated. The complexity of the gas phase ion processes observed suggest that, at present, caution should be exercised in using this approach for the analysis of environmental and other samples until our understanding of these processes increases considerably.
Related Topics
Physical Sciences and Engineering
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Analytical Chemistry
Authors
J.D. Barr, A.J. Bell, M. Bird, J.L. Mundy, J. Murrell, C.M. Timperley, P. Watts, F. Ferrante,