Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10558202 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2005 | 4 Pages |
Abstract
The interaction of the crown ether dibenzo-18-crown-6 (DBC) with iodine has been studied in CHCl3 at room temperature. The charge-transfer absorptions, far infrared and thermal measurements of the formed charge-transfer complex were recorded and discussed. The results obtained show the formation of the pentaiodide complex with the general formula [(DBC)]+ I5â. The pentaiodide ion, I5â, is described as I3â(I2) confirmed by the observation of the characteristic absorptions for I3â ion around 365 and 290 nm. In addition, the far infrared spectrum of the solid complex shows the three vibrations of I3â unit is at 141, 113 and 71 cmâ1 assigned to νas(I-I) and νs(I-I) and δ(I3â), respectively, while the band related to the vibration of I2 unit is observed at 180 cmâ1. Vibration analysis of the obtained data shows that the symmetry of I3â unit could be non-linear with C2v symmetry. The structure of the formed pentaiodide complex was further supported by thermal gravimetric analysis measurements.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
L.A. Shahada,