| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10559035 | Spectrochimica Acta Part B: Atomic Spectroscopy | 2005 | 16 Pages |
Abstract
A reaction model for hydride generation is proposed accounting for primary reactions giving rise to hydride formation through reaction intermediates, as well as side reactions involving D-H exchange and decomposition of reactive hydroboron species, reaction intermediates and final products. Hydrides are formed by direct hydrogen transfer from boron to the analyte atom, most likely through concerted mechanisms taking place via reaction intermediates.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Alessandro D'Ulivo, Zoltán Mester, Ralph E. Sturgeon,