Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10566088 | Ultrasonics Sonochemistry | 2014 | 7 Pages |
Abstract
A sonophotochemical oxidation process has been used for the treatment of an aqueous solution of phenol. The aim of this work is to evaluate the effect of nitrate ions on hydroxyl radical production and on phenol oxidation. It has been demonstrated that ultrasound can produce NOx (nitrate and nitrite), with a production rate of 2.2 μM minâ1. The photolysis of nitrate can significantly improve the hydroxyl radical production. The apparent rate constant for hydroxyl radical production increased from 0.0015 minâ1 to 0.0073 minâ1 while increasing initial nitrate concentration from 0 to 0.5 mM. The concentration of hydroxyl radical was directly proportional to the initial nitrate concentration. Using US/UV process, the apparent reaction rate constant of phenol degradation in the presence of nitrate reached 0.020 minâ1, which was relatively lower than the value obtained (0.027 minâ1) in the absence of nitrate. It appeared that, nitrate ions can inhibit the sonochemical degradation of organic compounds such as phenol.
Related Topics
Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
François Zaviska, Patrick Drogui, Errachid M. El Hachemi, Emmanuel Naffrechoux,