| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10569600 | Coordination Chemistry Reviews | 2013 | 19 Pages |
Abstract
⺠The development of coordination chemistry utilizing an extensive class of deprotonated pyridine/pyrazine-2-carboxamide and pyridine-2,6-dicarboxamide-based chelating ligands is discussed. ⺠Spin-state properties of Fe(III), oxidation level of metal-coordinated ligand, and high (â¥3) oxidation states of Fe, Co, Ni, and Ru have been presented. ⺠Differential behavior of five-/six-membered chelate ring formed by cobalt-coordinated alkyl-thioether is highlighted. ⺠Effect of donor atom type and metal stereochemistry on metal-centered E1/2 values has been critically analyzed.
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Authors
Amit Rajput, Rabindranath Mukherjee,