Article ID Journal Published Year Pages File Type
10569602 Coordination Chemistry Reviews 2013 13 Pages PDF
Abstract
► FeIVO, FeIII (η2O2), and FeIIIO2H complexes having a common ligand environment. ► Models of intermediates in oxygen activation by mononuclear nonheme iron enzymes. ► Axial ligands influence FeO bonding and spectroscopic properties of FeIVO complexes. ► Generation of FeIVO species by activating O implicates an FeIII-superoxo intermediate. ► Reactivity studies with model substrates establish catalytic potency of short-lived intermediates.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Authors
, , , , ,