Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10569604 | Coordination Chemistry Reviews | 2013 | 7 Pages |
Abstract
⺠Review of few examples of mononuclear heme-peroxo intermediates characterized by resonance Raman spectroscopy. ⺠Conversion of 7c side-on peroxo to 6c end-on hydroperoxo heme in the presence of heme axial ligation. ⺠Preparation and characterization of a ferric-peroxo heme model complex prepared using a sterically hindered porphyrin.
Keywords
EXAFSNRVSTMCTPPNuclear resonance vibrational spectroscopyNOSTMP1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane5,10,15,20-TetraphenylporphyrinDFTUV–VisHeme enzymeEDTAEthylene diamine tetra acetic acidUltraviolet–visibleImidazoleNDOElectron paramagnetic resonanceEPRNaphthalene dioxygenaseResonance Ramanextended X-ray absorption fine structureResonance Raman spectroscopyDioxygen activationInfraredDensity functional theorynitric oxide synthaseSeven-coordinateheme oxygenase
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Takehiro Ohta, Jin-Gang Liu, Yoshinori Naruta,