| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10569608 | Coordination Chemistry Reviews | 2013 | 14 Pages |
Abstract
⺠Metal K-edge X-ray absorption spectroscopy is a powerful geometric and electronic structure determination technique. ⺠Several factors affect the energy and intensity pattern of metal K-pre-edge and rising-edge regions. ⺠3d transition metals in bioinorganic sites activate O2 by forming transient metal-dioxygen intermediates. ⺠Supporting ligands play a crucial role in stabilizing electronic structure of M-O2 systems.
Keywords
β-DiketiminateEXAFSZeffMLCTTD-DFTtPAXANESLMCTnuclear magnetic resonance1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecaneDFTXASMetal to ligand charge transferLigand to metal charge transferTris(2-pyridylmethyl)amineNMRElectron paramagnetic resonanceEPRX-ray absorption near-edge spectroscopyResonance Ramanelectronic structureextended X-ray absorption fine structureEffective nuclear chargeBioinorganic chemistryX-ray absorption spectroscopyDensity functional theoryTime-dependent density functional theory
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ritimukta Sarangi,