| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10569610 | Coordination Chemistry Reviews | 2013 | 12 Pages |
Abstract
⺠The Cu coordination and location in zeolites is reviewed. ⺠Zeolites create a unique constrained microenvironment for Cu complexes (biomimics). ⺠Zeolites don't merely act as support, but alter the coordination chemistry of ligated copper ions. ⺠The reactive species for C-H bond activation in Cu-ZM-5 is a mono(μ-oxo)dicopper core. ⺠This mono(μ-oxo)dicopper core is related to the exceptional deNOx catalysis of Cu-ZSM-5.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Pieter Vanelderen, Julie Vancauwenbergh, Bert F. Sels, Robert A. Schoonheydt,