Article ID Journal Published Year Pages File Type
10569611 Coordination Chemistry Reviews 2013 16 Pages PDF
Abstract
► Fe(VI) oxidizes organic compounds by either 1 − e− or 2 − e− transfer step. ► Fe(V) reacts much faster with organic compounds than does Fe(VI). ► Fe(V) oxidizes compounds mostly by a concerted 2 − e− transfer step. ► Hammett-type relationships explain the mechanism of reactions.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Ferrate(VI) and ferrate(V) oxidation of organic compounds: Kinetics and mechanism
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