Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10569613 | Coordination Chemistry Reviews | 2013 | 13 Pages |
Abstract
⺠We discuss metal-salen phenoxyl radical complexes in the context of galactose oxidase modeling. ⺠Synthetic strategies for tuning electronic properties of salen ligands are discussed. ⺠Emphasis is placed on spectroscopic and electrochemical characterization of phenoxyl radical complexes as mixed-valent species along with a Marcus-Hush analysis of their intervalence charge transfer bands.
Keywords
SUMOTH+IVCTLMCTNIRDPVDFTXASVIsSalenG-valueUltravioletElectrochemistryIntervalence charge transferLigand-to-metal charge transferElectron paramagnetic resonanceEPRSuperconducting quantum interference devicePhenoxyl radicalResonance Ramanelectronic structureX-ray absorption spectroscopySpectroscopyTransition metalsVisibleRedox-active ligandsSquidNear-infraredDensity functional theoryDifferential pulse voltammetryCyclic voltammetryGalactose Oxidase
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Christopher T. Lyons, T. Daniel P. Stack,