| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10569615 | Coordination Chemistry Reviews | 2013 | 15 Pages |
Abstract
⺠Comprehensive evaluation of metal-ligand bond covalency in Ni(II)S4 complexes. ⺠Experimental evaluation of ground state orbital composition. ⺠Density functional theory dependence of NiS bonding. ⺠non-linearity of S K-edge transition dipole integrals as a function of S effective nuclear charge. ⺠Classical versus non-innocent coordination chemistry.
Keywords
DTCFWHHESEEMENDORRIXSNPGMNTBDTEXAFSGBLSUMOEDTXANESGGADFTXASK-edgeHomohighest occupied molecular orbitalEPRelectronic structureX-ray absorption spectroscopyX-ray photoelectron spectroscopyXPSLUMONon-innocent ligandsDensity functional theoryResonant inelastic X-ray scatteringLowest Unoccupied Molecular Orbital
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Electronic structure of [Ni(II)S4] complexes from S K-edge X-ray absorption spectroscopy](/preview/png/10569615.png "First Page Preview: Electronic structure of [Ni(II)S4] complexes from S K-edge X-ray absorption spectroscopy")
Authors
Matt S. Queen, Bradley D. Towey, Kevin A. Murray, Brad S. Veldkamp, Harlan J. Byker, Robert K. Szilagyi,