Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10569617 | Coordination Chemistry Reviews | 2013 | 12 Pages |
Abstract
⺠We synthesized new Mo(0) bis(dinitrogen) complexes with linear tetradentate phosphine ligands. ⺠We synthesized new Mo(0) monodinitrogen complexes with tripodal phosphine ligands. ⺠All Mo(0) dinitrogen complexes were spectroscopically characterized the reactivity of all Mo(0) dinitrogen complexes towards acids was investigated. ⺠A nitrogen fixing cycle based on Mo(0) dinitrogen complexes with pentaphosphine ligation was theoretically evaluated by DFT.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Henning Broda, Svea Hinrichsen, Felix Tuczek,