| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571096 | Inorganica Chimica Acta | 2011 | 7 Pages |
Abstract
⺠Six new chiral cis-dioxoMo(VI) complexes have been synthesized and characterized. ⺠The Complexes are studied for catalytic chiral sulfoxidation reactions with H2O2. ⺠Formation of oxoperoxoMo(VI) complexes during catalytic cycle was observed. ⺠Reactions resulted good to moderate ee with high yield of sulfoxide. ⺠Bulky substituent at specific position of the catalysts influences ee.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Rajan Deepan Chakravarthy, Kotapati Suresh, Venkatachalam Ramkumar, Dillip Kumar Chand,