Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571099 | Inorganica Chimica Acta | 2011 | 7 Pages |
Abstract
⺠Bis(2-thiophenyl)ditelluride, Tpn2Te2 (1) may be obtained from Te powder and TpnMgBr. ⺠Compound 1 has been employed to prepare Tpn2Te, TpnArTeCl2, Tpn2TeX2 and little known TpnTeX3. ⺠δ(13C, 125Te) of all and X-ray data of Tpn2TeBr2, Tpn2TeI2, TpnMesTeCl2 are discussed. ⺠Electronic and steric factors seem to affect the molecular geometry in solid state. ⺠Isomorphous Tpn2TeX2 (X = Br, I) show tetrameric supramolecular cubane-like framework.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ashok K.S. Chauhan, Poornima Singh, Ramesh C. Srivastava, Ray J. Butcher, Andrew Duthie,