Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571108 | Inorganica Chimica Acta | 2011 | 8 Pages |
Abstract
⺠μ-Chloro bridged cyclometallated Pd(II) complexes were readily prepared by reaction of Na2PdCl4 with benzylideneaniline. ⺠The reaction of Na2PdCl4 with Schiff-bases bearing a furyl or thienyl ring resulted in non-cyclometallated Pd(II) species. ⺠In di-μ-N3 bridged cyclometallated Pd(II) complexes the azido group bridged two Pd atoms through the same nitrogen atom. ⺠In di-μ-SCN bridged cyclometallated Pd(II) complexes the thiocyanato group bridged two Pd atoms through both S and N atoms.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yuchun Jiang, Yonglin Guo, Xia Zhu, Dandan Song, Yu Wang, Ximing Song, Francis Verpoort, Xiaohong Chang,