Article ID Journal Published Year Pages File Type
10571108 Inorganica Chimica Acta 2011 8 Pages PDF
Abstract
► μ-Chloro bridged cyclometallated Pd(II) complexes were readily prepared by reaction of Na2PdCl4 with benzylideneaniline. ► The reaction of Na2PdCl4 with Schiff-bases bearing a furyl or thienyl ring resulted in non-cyclometallated Pd(II) species. ► In di-μ-N3 bridged cyclometallated Pd(II) complexes the azido group bridged two Pd atoms through the same nitrogen atom. ► In di-μ-SCN bridged cyclometallated Pd(II) complexes the thiocyanato group bridged two Pd atoms through both S and N atoms.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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