Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571120 | Inorganica Chimica Acta | 2011 | 7 Pages |
Abstract
⺠Four [Ni(X-PhSO2NCS2)(dppe)] (X = H, Cl, Br, I) (1-4) complexes were obtained. ⺠Additionally, the [Ni(I-PhSO2NCS2)(PPh3)2] (5) complex was synthesized. ⺠The structures of the five complexes were determined by X-ray diffraction. ⺠Quantum chemical calculations are in accord with the spectroscopic and X-ray data. ⺠Rare C-H···Ni intramolecular preagostic interactions were observed in complexes 1-5.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Marcelo Ribeiro Leite Oliveira, Eduardo de Faria Franca, Celice Novais, Silvana Guilardi, Iterlandes Jr., Javier Ellena, Jorge Jr., Vito Modesto De Bellis, Mayura Marques Magalhães Rubinger,