Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571163 | Inorganica Chimica Acta | 2011 | 12 Pages |
Abstract
⺠Sterically bulky N2S heteroscorpionate ligands were complexed with Zn(II) and Cd(II). ⺠The solid state structures of the Zn(II) and Cd(II) complexes were determined to be mononuclear and dinuclear, respectively. ⺠DOSY NMR revealed the Zn(II) and Cd(II) complexes are mononuclear in solution. ⺠DFT calculations examined the impact of the N2S ligands on the electronic nature of the Zn(II) complexes.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Nicholas G. Spiropulos, G.C. Chingas, Mallory Sullivan, John T. York, Eric C. Brown,