| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571188 | Inorganica Chimica Acta | 2011 | 7 Pages |
Abstract
⺠Extension of the alkylation chemistry of [Pt2(μ-S)2(PPh3)4] towards fluorinated alkyl halides. ⺠X-ray structure of [Pt2(μ-S)(μ-SCH2C6F5)(PPh3)4]BPh4·2C6H6 shows Sâ¯C6F5 Ï interaction. ⺠Interaction holds C6F5 group above the {Pt2S2} core, in contrast to benzyle analogue.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Dinuclear platinum(II) sulfide-thiolate complexes [Pt2(μ-S)(μ-SR)(PPh3)4]+ containing fluorinated substituents and the identification of a Sâ¯C6F5 Ï interaction in the crystal structure of [Pt2(μ-S)(μ-SCH2C6F5)(PPh3)4]BPh4·2C6H6](/preview/png/10571188.png "First Page Preview: Dinuclear platinum(II) sulfide-thiolate complexes [Pt2(μ-S)(μ-SR)(PPh3)4]+ containing fluorinated substituents and the identification of a Sâ¯C6F5 Ï interaction in the crystal structure of [Pt2(μ-S)(μ-SCH2C6F5)(PPh3)4]BPh4·2C6H6")
Authors
William Henderson, Graham C. Saunders, T.S. Andy Hor,