| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571215 | Inorganica Chimica Acta | 2011 | 8 Pages |
Abstract
⺠In order to mimicking the active center of the VHPOs, we designed and synthesized a series of oxovanadium complexes containing aminoacid-derivatized ligands and characterized by X-ray single crystal diffraction. ⺠Based on the visible conversion of phenol red to bromophenol blue under weak-acid conditions, we investigated the role of the oxovanadium complexes in the bromide oxidation reaction. ⺠It is found that the oxovanadium (IV) complexes can be considered as potential functional model of vanadium-dependent haloperoxidases.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yun-Zhu Cao, Hai-Yan Zhao, Feng-Ying Bai, Yong-Heng Xing, Dong-Ming Wei, Shu-Yun Niu, Zhan Shi,