| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571226 | Inorganica Chimica Acta | 2011 | 8 Pages |
Abstract
⺠Interesting coordination behavior of 2-benzoylpyridine and copper(II) ion in basic medium has been studied depending upon the counter anion of the copper(II) salts used as reactant and the pH of the medium. ⺠The detailed structural study, reactivity towards catechol and CT-DNA with the help of spectroscopy, and the magnetic behavior at variable temperature of the new dinuclear copper(II) complex (3) has been discussed. ⺠Complex 3 is active to oxidize the catechol to the corresponding quinone in MeCN medium via complex-catechol intermediate. ⺠Magnetic behavior for 3 is typical for uncorrelated spins down even up to 2 K..
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Physical Sciences and Engineering
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Inorganic Chemistry
Authors
Sourav Dey, Sandipan Sarkar, Ennio Zangrando, Helen Stoeckli Evans, Jean-Pascal Sutter, Pabitra Chattopadhyay,