| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571238 | Inorganica Chimica Acta | 2011 | 5 Pages |
Abstract
⺠A novel cluster [Ag3I(dppm)2 WS4] (1) was prepared by substitution reaction, a new cluster [Ag4(SCN)2 (dppm)4 WS4]·H2O (2) was synthesized by 'one-pot' reaction. ⺠In synthesis of cluster 2, 1,10-phenathroline(phen) acts as catalysis. ⺠The coexistence of coordinated anion (SCNâ or Iâ) and bridging dppm ligand help to form span-new frameworks in clusters 1-2 which are beyond the fourteen fundamental skeletons founded for mono-Mâ² clusters.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Qiong-Hua Jin, Rong Wang, Ke-Yi Hu, Ye-Lan Xiao, Li-Na Cui, Cun-Lin Zhang,