| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571245 | Inorganica Chimica Acta | 2011 | 10 Pages |
Abstract
⺠A SCO complex [FeII(H2L2-3-2)](ClO4)2 was synthesized for studying its SCO property. ⺠The complex has the combination of the saturated chelate rings of 5-6-5 for H2L2-3-2. ⺠The complex showed a gradual and reversible one-step SCO without hysteresis. ⺠SCO was occurred by changing of ligand conformation and forming of hydrogen bonds. ⺠In LS state, space group was changed by changing thermodynamic stability of ligand.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Conformational effect of a spin crossover iron(II) complex: Bis[N-(2-methylimidazol-4-yl)methylidene-2-aminoethyl]propanediamineiron(II) perchlorate](/preview/png/10571245.png "First Page Preview: Conformational effect of a spin crossover iron(II) complex: Bis[N-(2-methylimidazol-4-yl)methylidene-2-aminoethyl]propanediamineiron(II) perchlorate")
Authors
Hiroaki Hagiwara, Akitsugu Kawano, Takeshi Fujinami, Naohide Matsumoto, Yukinari Sunatsuki, Masaaki Kojima, Hiroshi Miyamae,