Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571245 | Inorganica Chimica Acta | 2011 | 10 Pages |
Abstract
⺠A SCO complex [FeII(H2L2-3-2)](ClO4)2 was synthesized for studying its SCO property. ⺠The complex has the combination of the saturated chelate rings of 5-6-5 for H2L2-3-2. ⺠The complex showed a gradual and reversible one-step SCO without hysteresis. ⺠SCO was occurred by changing of ligand conformation and forming of hydrogen bonds. ⺠In LS state, space group was changed by changing thermodynamic stability of ligand.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Hiroaki Hagiwara, Akitsugu Kawano, Takeshi Fujinami, Naohide Matsumoto, Yukinari Sunatsuki, Masaaki Kojima, Hiroshi Miyamae,