Article ID Journal Published Year Pages File Type
10571686 Inorganica Chimica Acta 2005 10 Pages PDF
Abstract
Unit-valence parameters R0 were calculated for Tc-O bonds in Tc(VII)-Tc(III) compounds using data from X-ray crystal structures. A method was developed to estimate R0 values for given oxidation states and coordination numbers in order to verify the calculated values. The R0 values were used to evaluate bond distances and coordination numbers obtained from EXAFS models for several Tc compounds.
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Physical Sciences and Engineering Chemistry Inorganic Chemistry
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