| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571688 | Inorganica Chimica Acta | 2005 | 6 Pages |
Abstract
The oxidation of Ru(NH3)5NCCH2CN2+ complex by the peroxydisulfate ion in the aqueous solution yields two products, Ru(NH3)5NHCOCH2CN2+ with λmax = 373 nm and with λmax = 863 nm. The distribution of the products depends on the acidity of the solution with the formation of the binuclear complex favored at lower acid concentrations. A mechanism for the oxidation has been proposed by the kinetic studies in the region of 0.001-0.10 M acid concentrations.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Sunny Huang, Ingrid Lin, Sabina Wang, Joyce Yeh, Andrew Yeh,