Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571693 | Inorganica Chimica Acta | 2005 | 8 Pages |
Abstract
Three novel polymers of [2.2]paracyclophane(pcp) with in situ silver(I) perfluoro-dicarboxylates were synthesized and characterized. Complex 1 is constructed by pcp bridging columnar silver-anion chains. Complex 2 shows 3D pillared-layer structure in which disilver salts form 2D sheets and pcp act as pillars. Whereas complex 3 is 2-fold interpenetrated diamond structure. The effects of the dicarboxylate spacers and their conformations as well as the solvents on the formation of complexes are discussed.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Shu Qin Liu, Hisashi Konaka, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Yusaku Suenaga, Gui Ling Ning, Megumu Munakata,